The problem is that you are dealing with a flat head cap screw a soft material (like aluminum vs steel). When you tighten them down, the screw compresses the aluminum, and once it does, it's really in there. On top of that, if you're dealing with Aluminum, the dissimilar metals will cause some corrosion which is just about as good as loc-tite at keeping that bolt from ever coming loose.
If the threads have loc-tite on them, then you need to use some heat. Heat will break the loc-tite down.
If there's no loc-tite involved, I would start off with a good torx bit and some JB weld. Let the JB weld set up and cure for for over 24 hrs, then give it a try. If that doesn't work, you can try a hammer and center punch as mentioned above. If that fails, take a cobalt drill bit and drill the head off the bolt. Once the head has been removed, the tension will be released from the threads, and you should be able to carefully remove the remainder of the bolt. You may be able to spin the remainder of the bolt out with a hammer and center punch. If not, then I would try using a cut off wheel in a dremel tool to put a slot in the bolt, and then a small screwdriver to spin it out.
Just my 2 bits,
Mark